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SYNTHESIS OF (l ,2 -DI-O-PALMITOYL- rac -GLYCERO)-(β- D - GLUCOPYRANOSYL)PHOSPHATE
N. G. MOROSOVA, U. G. SACHKOVA, I. N. KRIVOICHENKO, G. A. SEREBRENNIKOVA, L. V. VOLKOVA, R. P. EVSTIGNEEVA
M. V. Lomonosov Institute of Fine Chemical Technology, Moscow
Abstract: A stereoselective synthesis of β-phosphatidylglucose based on glycosylation of benzyl-phosphatidic acid using D-glucose trichloroacetimidate' or 3, 4, 6-tri-O-acetyl-α-D-glucopyranose 1, 2-( tert-butyl orthoacetate) is described. Two different methods of the β-phosphatidylglucose synthesis have been investigated.
Russian Journal of Bioorganic Chemistry 1990, 16 (4):550-553